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- W1999745633 abstract "Laboratory and field studies were carried out in order to define the conditions necessary for the precipitation of Al in natural waters of pH 4–6. It is concluded that if precipitation does occur it involves the formation of Al(oxy)hydroxide, not aluminosilicates or basic aluminium sulphates. The solubility product of the Al(oxy)hydroxide is highly temperature dependent (ΔH = −30.5 kcal−1). It is also sensitive to concentrations of SO42− and, more markedly, humic substances (HS); both of these decrease solubility, HS by more than an order of magnitude at a concentration of approx. 5 mg l−1 (equivalent to approx. 2.5 mg l−1 dissolved organic carbon). A semi-empirical equation is proposed that allows the prediction of the effective solubility product at different temperatures and at humic concentrations in the range 0–7 mg l−1. Of the 113 natural water samples analysed, only one was calculated to be oversaturated with respect to Al(oxy)hydroxide." @default.
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- W1999745633 date "1988-05-01" @default.
- W1999745633 modified "2023-09-27" @default.
- W1999745633 title "Conditions required for the precipitation of aluminium in acidic natural waters" @default.
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- W1999745633 doi "https://doi.org/10.1016/0043-1354(88)90059-0" @default.
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