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- W1999755732 abstract "Abstract The decay rate constant k for the lowest triplet state of azulene (T1) can be determined from the time dependence of three kinetically different delayed luminescences: (1) delayed S2 → S0 fluorescence due to hetero triplet-triplet annihilation T1+T′1 ⇝ S2+S′0, where T′1 is the lowest triplet state of a sensitizer; (2) delayed S2→S0 fluorescence due to thermally activated homo triplet-triplet annihilation T1+T1⇝S2+S0; (3) phosphorescence and E-type delayed S1→S0 fluorescence. The kinetic and experimental conditions for the reliable determination of k are treated in detail. k has been determined between 130 and 270 K for azulene-h8 and azulene-d8 in isopentane. The temperature dependence of k can be represented by k=k0+k1 exp(−Ea/kBT). The values of k0,k1 and Ea are significantly different for azulene-h8 and azulene-d8." @default.
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- W1999755732 date "1993-08-01" @default.
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- W1999755732 title "The lowest triplet state of azulene-h8 and azulene-d8 in liquid solution. I. Survey, kinetic considerations, experimental technique, and temperature dependence of triplet decay" @default.
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- W1999755732 doi "https://doi.org/10.1016/0301-0104(93)87014-e" @default.
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