Matches in SemOpenAlex for { <https://semopenalex.org/work/W1999777640> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W1999777640 endingPage "1619" @default.
- W1999777640 startingPage "1611" @default.
- W1999777640 abstract "Oxidation of the chiral amines, (+) and (−)-isopinocampheylamine, with dimethyldioxirane (1) gives the corresponding nitro compounds with retention of configuration at the amine-bearing carbon atom. When lower amounts of 1 are used in the oxidation the amines give the nitroso dimers as the major products. Treatment of the nitroso dimer from the (−)-amine with additional 1 gave the same nitro compound as obtained from the amine oxidation. To further indicate that no racemization occurs during the amine oxidation we have synthesized the oxime of the nitroso intermediate and shown that it does not tautomerize under the reaction conditions." @default.
- W1999777640 created "2016-06-24" @default.
- W1999777640 creator A5041247258 @default.
- W1999777640 creator A5056651115 @default.
- W1999777640 creator A5082610094 @default.
- W1999777640 date "1996-06-01" @default.
- W1999777640 modified "2023-10-09" @default.
- W1999777640 title "Stereochemistry in the oxidation of primary amines to nitro compounds by dimethyldioxirane" @default.
- W1999777640 cites W1966403925 @default.
- W1999777640 cites W1966725812 @default.
- W1999777640 cites W1988226630 @default.
- W1999777640 cites W1989229072 @default.
- W1999777640 cites W1999834479 @default.
- W1999777640 cites W2001756927 @default.
- W1999777640 cites W2012549562 @default.
- W1999777640 cites W2019084282 @default.
- W1999777640 cites W2021412544 @default.
- W1999777640 cites W2026658044 @default.
- W1999777640 cites W2026871938 @default.
- W1999777640 cites W2043532642 @default.
- W1999777640 cites W2056717151 @default.
- W1999777640 cites W2057181998 @default.
- W1999777640 cites W2066874262 @default.
- W1999777640 cites W2084227462 @default.
- W1999777640 cites W2091101565 @default.
- W1999777640 cites W2092628009 @default.
- W1999777640 cites W2102860562 @default.
- W1999777640 cites W2950561600 @default.
- W1999777640 cites W2952655697 @default.
- W1999777640 cites W2952975467 @default.
- W1999777640 doi "https://doi.org/10.1016/0957-4166(96)00195-4" @default.
- W1999777640 hasPublicationYear "1996" @default.
- W1999777640 type Work @default.
- W1999777640 sameAs 1999777640 @default.
- W1999777640 citedByCount "18" @default.
- W1999777640 countsByYear W19997776402015 @default.
- W1999777640 countsByYear W19997776402016 @default.
- W1999777640 countsByYear W19997776402023 @default.
- W1999777640 crossrefType "journal-article" @default.
- W1999777640 hasAuthorship W1999777640A5041247258 @default.
- W1999777640 hasAuthorship W1999777640A5056651115 @default.
- W1999777640 hasAuthorship W1999777640A5082610094 @default.
- W1999777640 hasConcept C121332964 @default.
- W1999777640 hasConcept C1276947 @default.
- W1999777640 hasConcept C131779359 @default.
- W1999777640 hasConcept C155647269 @default.
- W1999777640 hasConcept C178790620 @default.
- W1999777640 hasConcept C185592680 @default.
- W1999777640 hasConcept C2775932965 @default.
- W1999777640 hasConcept C2777261567 @default.
- W1999777640 hasConcept C2777977315 @default.
- W1999777640 hasConcept C2779546866 @default.
- W1999777640 hasConcept C2779648554 @default.
- W1999777640 hasConcept C2780263894 @default.
- W1999777640 hasConcept C2780639532 @default.
- W1999777640 hasConcept C2909807293 @default.
- W1999777640 hasConcept C60002323 @default.
- W1999777640 hasConceptScore W1999777640C121332964 @default.
- W1999777640 hasConceptScore W1999777640C1276947 @default.
- W1999777640 hasConceptScore W1999777640C131779359 @default.
- W1999777640 hasConceptScore W1999777640C155647269 @default.
- W1999777640 hasConceptScore W1999777640C178790620 @default.
- W1999777640 hasConceptScore W1999777640C185592680 @default.
- W1999777640 hasConceptScore W1999777640C2775932965 @default.
- W1999777640 hasConceptScore W1999777640C2777261567 @default.
- W1999777640 hasConceptScore W1999777640C2777977315 @default.
- W1999777640 hasConceptScore W1999777640C2779546866 @default.
- W1999777640 hasConceptScore W1999777640C2779648554 @default.
- W1999777640 hasConceptScore W1999777640C2780263894 @default.
- W1999777640 hasConceptScore W1999777640C2780639532 @default.
- W1999777640 hasConceptScore W1999777640C2909807293 @default.
- W1999777640 hasConceptScore W1999777640C60002323 @default.
- W1999777640 hasIssue "6" @default.
- W1999777640 hasLocation W19997776401 @default.
- W1999777640 hasOpenAccess W1999777640 @default.
- W1999777640 hasPrimaryLocation W19997776401 @default.
- W1999777640 hasRelatedWork W1986286191 @default.
- W1999777640 hasRelatedWork W2045916830 @default.
- W1999777640 hasRelatedWork W2071105061 @default.
- W1999777640 hasRelatedWork W2341589740 @default.
- W1999777640 hasRelatedWork W2747611342 @default.
- W1999777640 hasRelatedWork W2953031353 @default.
- W1999777640 hasRelatedWork W3043032257 @default.
- W1999777640 hasRelatedWork W4240385869 @default.
- W1999777640 hasRelatedWork W4386771280 @default.
- W1999777640 hasRelatedWork W1496822730 @default.
- W1999777640 hasVolume "7" @default.
- W1999777640 isParatext "false" @default.
- W1999777640 isRetracted "false" @default.
- W1999777640 magId "1999777640" @default.
- W1999777640 workType "article" @default.