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• W1999803835 abstract "An accurate structure model of sodium-doped potassium titanyl phosphate, (Na 0.114 K 0.886 )K(TiO) 2 (PO 4 ) 2 , has been determined at 10.5 K by single-crystal X-ray diffraction. In addition to the low-temperature data, X-ray intensities have been collected at room temperature. When the temperature was decreased from room temperature to 10.5 K, both potassium cations moved 0.033 (2) Å along the c -axis, i.e. in the polar direction within the rigid Ti—O—P network. This alkaline metal ion displacement can be related to the Abrahams–Jamieson–Kurtz T C criteria for oxygen framework ferroelectrics. Potassium titanyl phosphate (KTP) is a well known material for second harmonic generation (SHG), and the influence of sodium dopant on the TiO 6 octahedral geometry and SHG is discussed. The material studied crystallizes in the space group Pna 2 1 with Z = 4, a = 12.7919 (5), b = 6.3798 (4), c = 10.5880 (7) Å, V = 864.08 (9) Å 3 , T = 10.5 (3) K and R = 0.023." @default.
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• W1999803835 date "2003-05-23" @default.
• W1999803835 modified "2023-09-26" @default.
• W1999803835 title "Cation movement and phase transitions in KTP isostructures; X-ray study of sodium-doped KTP at 10.5 K" @default.
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• W1999803835 doi "https://doi.org/10.1107/s0108768103008450" @default.
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