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- W1999806193 abstract "The crystal structure of Ta2VC2 has been determined from X-ray powder photographs. The structure is trigonal, space group D3d5-R3̄m, with a rhombohedral unit cell of ar = 7.481 Å, α = 23 ° 27' (hexagonal axes a = 3.045 Å, c = 21.81 Å). The unit cell contains 9 close packed metal layers in stacking sequence (hhc)3, or ABABCBCAC. The metal atoms are statistically distributed among point positions 3(a) and 6(c). It was not possible to decide by X-ray diffraction whether the carbon atoms are randomly distributed among the 9 octahedral interstitial sites in 6(c) and 3(b), or whether an ordered sublattice structure is formed. The phase is stable from room temperature to above 26oo °C. The homogeneity range at 1650 ° C varies between the limits (Ta1.80–2.04, V1.20–1.96)C1.74–1.80; the phase is thus substantially deficient in carbon." @default.
- W1999806193 created "2016-06-24" @default.
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- W1999806193 date "1970-01-01" @default.
- W1999806193 modified "2023-09-25" @default.
- W1999806193 title "The crystal structure of Ta2VC2" @default.
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- W1999806193 doi "https://doi.org/10.1016/0022-5088(70)90035-4" @default.
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