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• W1999835736 endingPage "374" @default.
• W1999835736 startingPage "359" @default.
• W1999835736 abstract "Rosuvastatin (RST), a synthetic statin, is a 3-hydroxy-3-methylglutaryl coenzyme A reductase inhibitor, with a number of pleiotropic properties, such as anti-inflammation, antioxidation and cardiac remodelling attenuation. According to IMS Health, rosuvastatin was the third best-selling drug in the United States in 2012. RST was recently found in European effluent samples at a detection frequency of 36%. In this study, we evaluate the identification process of major transformation products (TPs) of RST generated during the heterogeneous photocatalysis process with ZnO. The degradation of the parent molecule and the identification of the main TPs were studied in demineralised water. The TPs were monitored and identified by liquid chromatography-quadrupole time-of-flight mass spectrometry (LC–QTOF–MS/MS). Ten TPs were tentatively identified and some of them originated from the hydroxylation suffered by the aromatic ring during the initial stages of the process. Structural elucidation of some of the most abundant or persistent TPs was evaluated by computational analysis, which demonstrated that this approach can be used as a tool to help the elucidation of structures of unknown molecules. The analysis of the parameters obtained from ab initio calculations for different isomers showed the most stable structures and, consequently, the most likely to be found." @default.
• W1999835736 created "2016-06-24" @default.
• W1999835736 creator A5002609215 @default.
• W1999835736 date "1994-02-01" @default.
• W1999835736 modified "2023-10-17" @default.
• W1999835736 title "Use dependence of guanidinium toxins in frog myelinated nerve: Evidence for features of native voltage-gated sodium channels" @default.
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• W1999835736 doi "https://doi.org/10.1016/0301-0082(94)90080-9" @default.
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