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- W1999838467 abstract "A critical cluster in homogeneous nucleation can be defined in two ways. Thermodynamically, the size of the critical cluster corresponds to a maximum of the free energy of the system; kinetically the critical cluster is defined such that all supercritical clusters grow and all others decay. We describe the evolution of a cluster by a postulated stochastic master equation in which the transition probabilities are given by a formula proposed by Langer. We derive from these assumptions, by a path integral method, an equation for the most probable evolution of the size of the cluster and show thereby that under these circumstances the two definitions are equivalent." @default.
- W1999838467 created "2016-06-24" @default.
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- W1999838467 date "1975-10-01" @default.
- W1999838467 modified "2023-10-16" @default.
- W1999838467 title "A stochastic theory of cluster growth in homogeneous nucleation" @default.
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- W1999838467 doi "https://doi.org/10.1063/1.431744" @default.
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