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• W1999880906 abstract "The synthesis, magnetic and structural characterization of two tetrameric copper(II) complexes {N(C4H9)4}-[Cu2(LH)2(μ4-Br)Cu2(LH)2](PF6)4 (1) and [Cu2(LH)2(μ4-Cl)Cu2(LH)2](Cl)2(PF6) (2) is described. LH stands for the hemi-deprotonated anion of the tripodal aminophenol ligand N-(2-pyridylmethyl)-N,N-bis-[2′-hydroxy-5′-methyl-benzyl]-amine. The complexes are tetrametallic species formed around the central halide ion which behaves as an anion template for the formation of the tetranuclear species, by bridging two dimeric phenoxo bridged [Cu2(LH)2]2+ units. The magnetic behaviour is dominated by the strong antiferromagnetic exchange within the dimeric unit, mediated by the phenoxo bridges: J = −439(4) cm−1, g = 2.10(2) for (1) and J = −429(2) cm−1, g = 2.090(9) for (2)." @default.
• W1999880906 created "2016-06-24" @default.
• W1999880906 creator A5036370021 @default.
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• W1999880906 date "2014-07-01" @default.
• W1999880906 modified "2023-10-01" @default.
• W1999880906 title "The templating effect of halides in the tetrameric copper(II) [Cu2(LH)2(μ4-X)Cu2(LH)2]3+ complexes (LH2=N-(2-pyridylmethyl)-N,N-bis-[2′-hydroxy-5′-methyl-benzyl]-amine; X=Br, Cl). Synthesis and magneto-structural characterization" @default.
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• W1999880906 doi "https://doi.org/10.1016/j.poly.2014.03.048" @default.
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