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- W1999899609 abstract "The kinetics of the reaction between atomic fluorine and CF3Br has been investigated in the temperature range 188–373 °K using molecular beam analysis in conjunction with an H2 titration to measure the concentration of atomic fluorine in a flow reactor. The effective second order rate constant for this reaction varies from 2.5 × 108 cm3/mole · sec at 373 °K to 8 × 109 cm3/mole · sec at 188 °K. This unusual temperature dependence, as well as the pressure dependence of the effective rate constant, is explained by a mechanism involving the formation of a stable pseudotrihalogen radical CF3BrF. The radical reacts with atomic fluorine by competing pathways that result in either net recombination of atomic fluorine or net consumption of CF3Br. In agreement with the proposed mechanism, CF3Br is found to be at least 12 times more efficient than CF4 as a catalyst for the recombination of fluorine atoms." @default.
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- W1999899609 date "1973-10-01" @default.
- W1999899609 modified "2023-09-26" @default.
- W1999899609 title "Reaction between atomic fluorine and CF3Br: Evidence for a pseudotrihalogen radical intermediate" @default.
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- W1999899609 doi "https://doi.org/10.1063/1.1680535" @default.
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