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- W1999935634 abstract "Abstract The attenuated total reflection (ATR) spectra of hexamethylbenzene (HMB)-tetracyanoethylene (TCNE) complexes, 1:1 and 2:1 complexes, have been measured in polycrystalline state. From the reflectivity curves in perpendicular polarization, the optical constants, n and k , and absorption coefficient α were calculated for the fundamental bands. Then the integrated absorption intensities were obtained. For the CC stretching band of TCNE induced with complex formation the intensity is obtained to be 1.60 × 10 3 cm m.mole −1 = 16.0 Km mol −1 for the 1:1 complex, and 3.39 × 10 3 cm m.mole −1 = 33.9 Km mol −1 for the 2:1 complex. The intensity of the CH 3 stretching band for the 2:1 complex is 1.77 × 10 3 cm m.mole −1 = 17.7 Km mol −1 (per one HMB). The induced bands are, thus, as strong as those of the i.r. active fundamental bands of the components. The cause of the induced bands is discussed." @default.
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- W1999935634 date "1976-01-01" @default.
- W1999935634 modified "2023-10-17" @default.
- W1999935634 title "Infrared optical constants and absorption intensities of hexamethylbenzene-tetracyanoethylene complexes" @default.
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- W1999935634 doi "https://doi.org/10.1016/0584-8539(76)80193-6" @default.
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