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- W1999946061 abstract "A wide variety of chemical reactions have been observed in organic compounds subjected to shock loading [1]. A shock wave in condensed media produces a unique and violent environment which is characterized by high pressure, elevated temperature, strong shear forces, and large rates of change of these parameters. The resulting conditions on the molecular size scale are not well understood at present, but seem to produce both static and dynamic damage to both the lattice structure and the molecular structure which serves, in some cases, to greatly accelerate reaction rates relative to equivalent, but static, conditions of temperature and pressure [1]. For instance, there are examples of shock-induced polymerizations occurring perhaps ten orders of magnitude faster than is seen in conventional processes, and also reactions which only occur conventionally via the action of a catalyst which occur with large yield under shock loading. Such unusual reactive processes provide a probe into the molecular-scale environment of a shocked material, since chemistry almost always takes place between neighboring molecules." @default.
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- W1999946061 date "1986-01-01" @default.
- W1999946061 modified "2023-09-27" @default.
- W1999946061 title "Subthreshold Generation of Free Radicals in Shock-Loaded Organic Solids" @default.
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- W1999946061 doi "https://doi.org/10.1007/978-1-4613-2207-8_132" @default.
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