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• W1999967541 abstract "A series of titanium complexes [(Ar)NC(CF3)CHC(R)O]2TiCl2 (4b: Ar = –C6H4OMe(p), R = Ph; 4c: Ar = –C6H4Me(p), R = Ph; 4d: Ar = –C6H4Me(o), R = Ph; 4e: Ar = α-Naphthyl, R = Ph; 4f: Ar = –C6H5, R = t-Bu; 4g: Ar = –C6H4OMe(p); R = t-Bu; 4h: Ar = –C6H4Me(p); R = t-Bu; 4i: Ar = –C6H4Me(o); R = t-Bu) has been synthesized and characterized. X-ray crystal structures reveal that complexes 4b, 4c and 4h adopt distorted octahedral geometry around the titanium center. With modified methylaluminoxane (MMAO) as a cocatalyst, complexes 4b–c and 4f–i are active catalysts for ethylene polymerization and ethylene/norbornene copolymerization, and produce high molecular weight polyethylenes and ethylene/norbornene alternating copolymers. In addition, the complex 4c/MMAO catalyst system exhibits the characteristics of a quasi-living copolymerization of ethylene and norbornene with narrow molecular weight distribution." @default.
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• W1999967541 date "2005-07-01" @default.
• W1999967541 modified "2023-10-10" @default.
• W1999967541 title "Titanium complexes bearing aromatic-substituted β-enaminoketonato ligands: Syntheses, structure and olefin polymerization behavior" @default.
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• W1999967541 doi "https://doi.org/10.1016/j.jorganchem.2005.04.002" @default.
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