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- W1999979427 abstract "A mixture of saccharide primers with partially fluorinated tails, 2-(perfluorooctyl)ethyl 4′- O -(β- d -galactopyranosyl)-β- d -glucopyranoside (Lac H2F8) and 6-(perfluorohexyl)hexyl 2′-acetamido-2′-deoxy-β- d -glucopyranoside (GN H6H6), were introduced to animal cells. The oligosaccharide of Lac H2F8 was elongated by cellular enzymes and gave a GM3-type oligosaccharide. On the other hand, GN H6F6 was galactosylated to afford a lactosamine derivative that was further sialylated. This research confirmed that simultaneous glycosylation processes took place for Lac H2F8 and GN H6F6 primers and that the presence of one did not prevent the glycosylation of the other from proceeding. Each primer was recognized independently and elongated sequentially by cellular enzymes. Significantly, the synthesis of glycolipids from a mixture of these artificial scaffolds did not prevent the synthesis of glycolipids from the natural precursor. The glycosyl transferases recognized both precursors resulting to simultaneous synthesis of glycolipids." @default.
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- W1999979427 date "2010-05-01" @default.
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- W1999979427 title "Fluorous tag method for the simultaneous synthesis of different kinds of glycolipids" @default.
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- W1999979427 doi "https://doi.org/10.1016/j.jfluchem.2010.02.001" @default.
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