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- W1999993018 abstract "Abstract The reaction of [Os3(CO)10(μ-dppm)] (1) with 1-vinylimidazole at 110°C afforded two novel trosmium compounds, [(μ -H)Os 3 (CO) 7 (μ-2,3-η 2 - C=NCH=CHN CH=CH 2 ) (η 1 - CH=NCH=CHN –CH=CH2){μ3-η3-PPhCH2PPh(C6H4)}] (3) and [Os3(CO)8(μ-2,3-η2- C=NCH=CHN CH=CH 2 )(η1- CH=NCH=CHN CH=CH 2 )(μ3-η2-PPhCH2PPh2)] (4). The compounds have been characterized by elemental analysis, IR, 1H and 31P{1H} NMR and mass spectrometry together with an X-ray analysis for 3, which has a unique structure with a bridging hydride, an N-coordinated η1-vinylimidazole, a dimetallated μ-η2-vinylimidazolide and a μ3-η3-PPhCH2PPh(C6H4) ligands." @default.
- W1999993018 created "2016-06-24" @default.
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- W1999993018 date "2000-11-01" @default.
- W1999993018 modified "2023-09-26" @default.
- W1999993018 title "Novel triosmium clusters derived from the reaction of [Os3(CO)10(μ-dppm)] with 1-vinylimidazole" @default.
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- W1999993018 doi "https://doi.org/10.1016/s1387-7003(00)00140-4" @default.
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