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• W2000002127 abstract "The gas-phase molecular structure of 2,2-dimethyl-1,3-dioxa-2-silacyclohexane, (CH3)2Si(OCH2)2(CH2), has been determined by electron diffraction at 290 K nozzle temeperature. The electron diffraction data are consistent with a chair conformation of the six-membered ring having CS symmetry, while the presence of smaller amounts of other conformers cannot be excluded. The following bond lengths rg) and bond angles were obtained: SiO = 1.651 ± 0.003 Å, SiC = 1.863 ± 0.004 Å, CC = 1.529 ± 0.003 Å, OC = 1.425 ± 0.003 Å, (CH)mean = 1.125 ± 0.003 Å, OSiO = 108.9 ± 0.4°, OSiC = 108.5 ± 0.2°, CSiC = 113.9 ± 0.6°, SiOC = 118.5 ± 0.3°, CCC = 112.2 ± 0.4°, (SiCH)mean = 109.1 ± 0.7°, (HC The flap angle characterizing the orientation of the OSiO plane with respect to the four coplanar atoms of the ring (O, C, C, O) is considerably smaller than the corresponding angle in cyclohexane (27° vs. 50°) indicating flattening of the ring in the vicinity of the Si heteroatom. The flap of the opposite end of the ring is similar to that of cyclohexane." @default.
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• W2000002127 date "1993-05-01" @default.
• W2000002127 modified "2023-10-18" @default.
• W2000002127 title "Molecular structure of 2,2-dimethyl-1,3-dioxa-2- silacyclohexane from gas-phase electron diffraction" @default.
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• W2000002127 doi "https://doi.org/10.1016/0022-2860(93)85015-m" @default.
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