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- W2000004198 abstract "We report on the preparation and characterization of self-assembled monolayers from aliphatic thiols with different chain length and termination on InAs (100) planar surfaces. This included as first step the development and investigation of a thorough chemical InAs surface preparation step using a dedicated bromine/NH4OH-based etching process. Ellipsometry, contact angle measurements and atomic force microscopy (AFM) indicated the formation of smooth, surface conforming monolayers. The molecular tilt angles were obtained as 30 ± 10° with respect to the surface normal. Kelvin probe force microscopy (KPFM) measurements in hand with Parameterized Model number 5 (PM5) calculations of the involved molecular dipoles allowed for an estimation of the molecular packing densities on the surface. We obtained values of up to n = 1014 cm− 2 for the SAMs under study. These are close to what is predicted from a simple geometrical model that would calculate a maximum density of about n = 2.7 × 1014 cm− 2. We take this as additional conformation of the substrate smoothness and quality of our InAs–SAM hybrid layer systems." @default.
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- W2000004198 date "2015-03-01" @default.
- W2000004198 modified "2023-09-26" @default.
- W2000004198 title "Self-assembled monolayers of alkyl-thiols on InAs: A Kelvin probe force microscopy study" @default.
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- W2000004198 doi "https://doi.org/10.1016/j.susc.2014.11.023" @default.
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