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• W2000076207 abstract "Thin films of 4-hydroxy-TEMPO-substituted TTF [TTF-(OH)TEMPO] were grown on ex situ cleaved KBr (001) using the high vacuum evaporation technique. Sub-micronic grains uniformly covering the KBr surface were evidenced by scanning electron microscopy (SEM). The films were also studied by infrared (IR), electron spin resonance spectroscopy (ESR) and X-ray photoelectron spectroscopy (XPS). Amorphous thin films of [TTF-(OH)TEMPO][TCNQ] were obtained on KBr pellets and on micro-rough Si(001) wafers using chemical vapour deposition (CVD). They were characterized by SEM, IR, XPS and ESR. SEM images on micro-rough Si(001) wafers evidenced micro-needles (0.5–2 μm in length, 0.1–0.2 μm in diameter), uniformly covering the substrate surface. CN stretching frequencies were in agreement with a reduced TCNQ moiety, thus indicating a charge transfer between the donor [TTF-(OH)TEMPO] and the acceptor (TCNQ) molecules (degree of charge transfer ∼1)." @default.
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• W2000076207 date "2002-05-31" @default.
• W2000076207 modified "2023-09-25" @default.
• W2000076207 title "Thin films of hydroxy-TEMPO-substituted TTF and of its charge-transfer complex with TCNQ" @default.
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• W2000076207 doi "https://doi.org/10.1039/b111662m" @default.
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