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- W2000102394 abstract "The 1H and 13C NMR spectra of the 2-methylperhydro-9b-azaphenalene alkaloids characteristic of coccinellid beetles, myrrhine, precoccinelline, hippodamine, their N-oxides and the corresponding hydrochlorides were completely assigned for the first time by a one- and two-dimensional homo- and heteronuclear study (1H, 13C, 1H–1 H COSY, HMQC, HMBC) at 600 and 150.87 MHz. The influence of the ring junction stereochemistry and of the N-oxide function on the proton and carbon chemical shifts in this series of compounds is discussed. Protonation shifts are also considered © 1999 John Wiley & Sons, Ltd." @default.
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- W2000102394 date "1999-01-01" @default.
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- W2000102394 title "Complete assignment of the1H and13C NMR spectra of the Coccinellidae-defensive alkaloids myrrhine, precoccinelline and hippodamine, theirN-oxides and the corresponding hydrochlorides" @default.
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- W2000102394 doi "https://doi.org/10.1002/(sici)1097-458x(199901)37:1<60::aid-mrc417>3.0.co;2-g" @default.
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