Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000111456> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W2000111456 endingPage "349" @default.
- W2000111456 startingPage "343" @default.
- W2000111456 abstract "1H and 13C NMR spectra of the novel marine macrolide swinholide-A, which provide the basis for its structure elucidation, have been completely assigned by parallel use of 1D and homo- and hetero-nuclear 2D NMR techniques. Swinholide-A (1) probably a polyketide, is a 22-membered macrolide embodying a dihydropyran ring and a 10-carbon side-chain ending with a substituted tetrahydropyran ring. The high degree of overlap of eleven CH—O and nine CH2 signals in the 1D proton NMR spectrum of 1 necessitated the structure elucidation of swinholide-A tetraformate (2) by 2D homo- (up to 6J with formyl groups) and hetero-nuclear NMR correlations. Formyl groups can be good structural probes in complex polyalcohols, as shown by the observed 5J and 6J formate couplings in 2." @default.
- W2000111456 created "2016-06-24" @default.
- W2000111456 creator A5044714615 @default.
- W2000111456 creator A5060600887 @default.
- W2000111456 creator A5084956907 @default.
- W2000111456 date "1986-04-01" @default.
- W2000111456 modified "2023-09-27" @default.
- W2000111456 title "Swinholide-A, a new marine macrolide. Complete assignment of1H and13C spectra by 2D NMR techniques" @default.
- W2000111456 cites W1999890029 @default.
- W2000111456 cites W2010528272 @default.
- W2000111456 cites W2054630101 @default.
- W2000111456 cites W2949880641 @default.
- W2000111456 doi "https://doi.org/10.1002/mrc.1260240414" @default.
- W2000111456 hasPublicationYear "1986" @default.
- W2000111456 type Work @default.
- W2000111456 sameAs 2000111456 @default.
- W2000111456 citedByCount "15" @default.
- W2000111456 countsByYear W20001114562021 @default.
- W2000111456 crossrefType "journal-article" @default.
- W2000111456 hasAuthorship W2000111456A5044714615 @default.
- W2000111456 hasAuthorship W2000111456A5060600887 @default.
- W2000111456 hasAuthorship W2000111456A5084956907 @default.
- W2000111456 hasConcept C100705429 @default.
- W2000111456 hasConcept C103319777 @default.
- W2000111456 hasConcept C111429119 @default.
- W2000111456 hasConcept C116447816 @default.
- W2000111456 hasConcept C121332964 @default.
- W2000111456 hasConcept C1276947 @default.
- W2000111456 hasConcept C147789679 @default.
- W2000111456 hasConcept C161790260 @default.
- W2000111456 hasConcept C163111631 @default.
- W2000111456 hasConcept C178790620 @default.
- W2000111456 hasConcept C185592680 @default.
- W2000111456 hasConcept C19549132 @default.
- W2000111456 hasConcept C2776305277 @default.
- W2000111456 hasConcept C2777728192 @default.
- W2000111456 hasConcept C2780378348 @default.
- W2000111456 hasConcept C4839761 @default.
- W2000111456 hasConcept C66974803 @default.
- W2000111456 hasConcept C67787023 @default.
- W2000111456 hasConcept C71240020 @default.
- W2000111456 hasConceptScore W2000111456C100705429 @default.
- W2000111456 hasConceptScore W2000111456C103319777 @default.
- W2000111456 hasConceptScore W2000111456C111429119 @default.
- W2000111456 hasConceptScore W2000111456C116447816 @default.
- W2000111456 hasConceptScore W2000111456C121332964 @default.
- W2000111456 hasConceptScore W2000111456C1276947 @default.
- W2000111456 hasConceptScore W2000111456C147789679 @default.
- W2000111456 hasConceptScore W2000111456C161790260 @default.
- W2000111456 hasConceptScore W2000111456C163111631 @default.
- W2000111456 hasConceptScore W2000111456C178790620 @default.
- W2000111456 hasConceptScore W2000111456C185592680 @default.
- W2000111456 hasConceptScore W2000111456C19549132 @default.
- W2000111456 hasConceptScore W2000111456C2776305277 @default.
- W2000111456 hasConceptScore W2000111456C2777728192 @default.
- W2000111456 hasConceptScore W2000111456C2780378348 @default.
- W2000111456 hasConceptScore W2000111456C4839761 @default.
- W2000111456 hasConceptScore W2000111456C66974803 @default.
- W2000111456 hasConceptScore W2000111456C67787023 @default.
- W2000111456 hasConceptScore W2000111456C71240020 @default.
- W2000111456 hasIssue "4" @default.
- W2000111456 hasLocation W20001114561 @default.
- W2000111456 hasOpenAccess W2000111456 @default.
- W2000111456 hasPrimaryLocation W20001114561 @default.
- W2000111456 hasRelatedWork W2000111456 @default.
- W2000111456 hasRelatedWork W2000288922 @default.
- W2000111456 hasRelatedWork W2001259470 @default.
- W2000111456 hasRelatedWork W2064174597 @default.
- W2000111456 hasRelatedWork W2073286828 @default.
- W2000111456 hasRelatedWork W2086169404 @default.
- W2000111456 hasRelatedWork W2131219719 @default.
- W2000111456 hasRelatedWork W2359461102 @default.
- W2000111456 hasRelatedWork W2609973409 @default.
- W2000111456 hasRelatedWork W3197623521 @default.
- W2000111456 hasVolume "24" @default.
- W2000111456 isParatext "false" @default.
- W2000111456 isRetracted "false" @default.
- W2000111456 magId "2000111456" @default.
- W2000111456 workType "article" @default.