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- W2000117664 abstract "The critical brush density, where transition from carpet-only structure to carpet/brush double-layered structure occurs, was estimated for a weakly ionic amphiphilic diblock copolymer, (diethylsilacyclobutane)34-b-(methacrylic acid)50, monolayer on water by an in situ X-ray reflectivity technique. The brush density in the monolayer was controlled from 0.11 to 0.60 brush chain/nm2 by changing surface pressure and mixing a poly(diethylsilacyclobutane) homopolymer separately synthesized. Only a carpet layer was formed at a low brush density condition, but a carpet and brush double layer was found for a higher brush density of more than 0.48/nm2. This brush density, which is fairly high, would be valuable for discussing the polyelectrolyte brush nanostructure." @default.
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- W2000117664 date "2005-06-21" @default.
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- W2000117664 title "Critical Brush Density for the Transition between Carpet-Only and Carpet/Brush Double-Layered Structures<sup>1</sup>" @default.
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- W2000117664 doi "https://doi.org/10.1021/la047188a" @default.
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