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• W2000120788 abstract "Abstract Oxidation of SiC is a major constraint during development of metal oxide–silicon carbide composites when processed in oxygen containing environment such as in air. In the present investigation, Mg+2, Al+3 and Zr+4 hydrogels were used as a source of respective oxide and oxidation of SiC in each system was studied. A three-stage mechanism was found to be operative in Al+3 and Zr+4 systems where oxidation at the initial stages was found to be controlled by the nature of the polynuclear complexes formed on the surfaces of SiC particles. At the intermediate stage a transition from polynuclear complex to metal silicate protective layer formation changes the oxidation characteristics. Finally the metal silicates provided the ultimate protection. Mg+2 was found to be ineffective. The extent of retention of SiC in the final composites could be premonitored by controlling the amount and the nature of complexing cations." @default.
• W2000120788 created "2016-06-24" @default.
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• W2000120788 date "2000-11-01" @default.
• W2000120788 modified "2023-09-27" @default.
• W2000120788 title "Retention of SiC during development of SiC-MxSiyOz composites [M=Al, Zr, Mg] by reaction bonding in air" @default.
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• W2000120788 doi "https://doi.org/10.1016/s0955-2219(00)00082-0" @default.
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