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• W2000120980 abstract "In situ x-ray photoelectron spectroscopy was used to study the oxidation of niobium films covered by some monolayers of cerium. Significant amounts of ${mathrm{Nb}}_{2}$${mathrm{O}}_{5}$ are formed at pressures as low as 6.6 ifmmodetimeselsetexttimesfi{} ${10}^{ensuremath{-}6}$ Pa, promoted by the cerium overlayer. This catalytic activity is related to the trivalent-to-tetravalent valence change of the cerium during oxidation. The kinetics of ${mathrm{Nb}}_{2}$${mathrm{O}}_{5}$ formation beneath the oxidized cerium shows two stages; the first is fast growth limited by ion diffusion, the second is slow growth by electron tunneling." @default.
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• W2000120980 date "1984-08-27" @default.
• W2000120980 modified "2023-09-26" @default.
• W2000120980 title "Catalytic Oxidation of Niobium" @default.
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• W2000120980 doi "https://doi.org/10.1103/physrevlett.53.948" @default.
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