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- W2000127128 abstract "A study of the vapor pressures of the primary alcohols L-propanol through L-octanol as a function of their concentration in isooctane at 25°C has been interpreted in terms of a self-association model. The results suggest that in fairly dilute solutions (0.05–1 M), the self-association tendencies of these alcohols are independent of chain length and can be described adequately with a monomer-pentamer association model. At higher concentrations and in the pure liquids, the extent of association increases with decreasing chain length. Standard free energies for the processes of transferring alcohol from its pure state to vapor, from its pure state to infinite dilution in isooctane, and from infinite dilution in isooctane to the vapor phase have been calculated. The methylene group contribution to the free energy of transfer of alcohol from infinite dilution in isooctane to the vapor phase has been shown to be a constant equal to 710 cal/mole of -CH2- groups." @default.
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- W2000127128 date "1978-01-01" @default.
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- W2000127128 title "Vapor pressure studies of self-association of alcohols in isooctane. I. the effect of chain length" @default.
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- W2000127128 doi "https://doi.org/10.1016/0378-5173(78)90033-9" @default.
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