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- W2000128872 abstract "The degradation of phenylarsonic acid (PA) and its derivatives by hydrothermal treatment (HTT) was examined, especially focusing on the effect of adding H2O2 upon the degradation efficiency. The degradation was assessed by the generation of arsenate resulting from the cleavage of AsC bonds in the PA derivatives. When PA (without substituents) was subjected to an HTT with H2O2 (H2O2-HTT; 0.5–1% H2O2) at 175–200 °C, PA was almost completely degraded into arsenate, whereas an HTT with NaOH (NaOH-HTT; 3 M NaOH) at the temperatures provided almost no degradation. The H2O2-HTT also worked well for the degradation of PA derivatives with hydroxy and/or nitro groups on the phenyl ring. However, the degradation of aminophenylarsonic acids was not favorably performed by the H2O2-HTT. The effect of the structure of PA derivatives upon the degradation susceptibility was discussed. A photocatalytic reaction using TiO2 was also attempted for the degradation of PA derivatives. Copyright © 2005 John Wiley & Sons, Ltd." @default.
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- W2000128872 date "2005-01-01" @default.
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- W2000128872 title "Degradation of phenylarsonic acid and its derivatives into arsenate by hydrothermal treatment and photocatalytic reaction" @default.
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- W2000128872 doi "https://doi.org/10.1002/aoc.720" @default.
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