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- W2000147720 abstract "Two new C2v cavitands based on resorcin[4]arene were synthesized and their binding properties for nine small molecules were studied. The alcohol selectivity was in the order of CH3OH∼CH3CHOHCH3<CH3CH2CH2OH≪CH3CH2OH with the highest Ka=260 M−1 at 23°C in CDCl3. Their carceroisomerism was observed by 1H NMR spectra and the quinone-capped cavitand's complexation of ethanol was driven entropically." @default.
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- W2000147720 date "2001-03-01" @default.
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- W2000147720 title "Versatile cavitands for small molecules: the entropically driven ethanol selectivity" @default.
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- W2000147720 doi "https://doi.org/10.1016/s0040-4039(01)00023-5" @default.
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