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- W2000175420 abstract "Sorption of hydrochloric and perchloric acids and their sodium salts was studied by Cl− and ClO4− forms of ion exchanger Dowex 1×8 in the concentration range of the external electrolyte 0.25–4 mol/l. Sorption of water and the total amount of the solution were also studied. Sorption of the acid appeared markedly higher than that of the respective salts. A mathematical modeling and computer simulation of the processes were performed. The overall sorption was represented as a superposition of the Donnan membrane distribution and formation associates type RAn · (AnKt)i · (H2O)n in the homogeneous resin phase. The model expresses non-ideality of the resin phase in explicit form as formation of the above associates characterized by the constants of their formation. A good agreement between the experimental and calculated sorption in the whole concentration range was obtained in the assumption of two associates with i=1, 2 and n=1–3. The same factors control sorption of the acids and the salts and the difference in their behavior has a quantitative character. The main introduction into the overall sorption of the salts makes the Donnan distribution up to concentration of the external electrolyte 4 M, while the main part of the absorbed acids is contained in the associates." @default.
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- W2000175420 date "2004-07-01" @default.
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- W2000175420 title "Non-exchange sorption of electrolytes by ion exchangers" @default.
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- W2000175420 doi "https://doi.org/10.1016/j.reactfunctpolym.2004.02.009" @default.
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