FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000183244> ?p ?o ?g. }

• W2000183244 endingPage "108" @default.
• W2000183244 startingPage "100" @default.
• W2000183244 abstract "The one-electron reduction of vitamin B1 2 and its coenzyme has been studied by γ-irradiating the frozen methanolic solutions of these compounds. A new optical absorption spectrum was obtained by γ-irradiation of aqueous methanol solution of vitamin B1 2 at 77°K; this spectrum changed by slight warming to that of B1 2 r. ESR spectra were also recorded. The ESR signal at g ≈ 2.3 for the irradiated solution at 77°K was ascribed to the vitamin B1 2 anion, in which an unpaired electron is localized in the σ★ orbital of the cobalt-ligand bond. Upon slight warming the ESR signal changed to that of B1 2 r. In contrast to the vitamin, the ESR spectrum of irradiated coenzyme B1 2 solution in C2 H3 O2 H3 + 2H2 O at 77°K showed no signal due to a paramagnetic cobalt complex but an asymmetric signal of g ≈ 2.0, which is attributable to an organic radical presumably derived from the adenosyl group. The optical spectrum indicates the formation of B1 2 s (diamagnetic) by the CoC bond cleavage. Upon slight warming the optical and ESR spectra changed to those ascribed to B1 2 r. The present study thus revealed that the one-electron reduction of vitamin B1 2 and its coenzyme B1 2 gives rise to the heterolytic cleavage of the CoC bonds by the selective attack of electrons, and the former produces B1 2 r and the latter, B1 2 s." @default.
• W2000183244 created "2016-06-24" @default.
• W2000183244 creator A5023953446 @default.
• W2000183244 creator A5077186384 @default.
• W2000183244 creator A5079069712 @default.
• W2000183244 date "1974-11-04" @default.
• W2000183244 modified "2023-09-26" @default.
• W2000183244 title "The cleavage of the carbon-cobalt bond in vitamin B1 2 and coenzyme B1 2 by reduction with electrons in γ-irradiated frozen solutions" @default.
• W2000183244 cites W1488811017 @default.
• W2000183244 cites W1514508191 @default.
• W2000183244 cites W1552281684 @default.
• W2000183244 cites W1607626549 @default.
• W2000183244 cites W1625220772 @default.
• W2000183244 cites W1967404522 @default.
• W2000183244 cites W1972254931 @default.
• W2000183244 cites W1972823667 @default.
• W2000183244 cites W1975835403 @default.
• W2000183244 cites W1976951969 @default.
• W2000183244 cites W1988836698 @default.
• W2000183244 cites W1993618100 @default.
• W2000183244 cites W2005555085 @default.
• W2000183244 cites W2016099899 @default.
• W2000183244 cites W2021443438 @default.
• W2000183244 cites W2027871465 @default.
• W2000183244 cites W2052472037 @default.
• W2000183244 cites W2061836446 @default.
• W2000183244 cites W2067858895 @default.
• W2000183244 cites W2068497257 @default.
• W2000183244 cites W2072139098 @default.
• W2000183244 cites W2082860573 @default.
• W2000183244 cites W2090247043 @default.
• W2000183244 cites W2301273031 @default.
• W2000183244 doi "https://doi.org/10.1016/0304-4165(74)90076-2" @default.
• W2000183244 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/4371859" @default.
• W2000183244 hasPublicationYear "1974" @default.
• W2000183244 type Work @default.
• W2000183244 sameAs 2000183244 @default.
• W2000183244 citedByCount "6" @default.
• W2000183244 crossrefType "journal-article" @default.
• W2000183244 hasAuthorship W2000183244A5023953446 @default.
• W2000183244 hasAuthorship W2000183244A5077186384 @default.
• W2000183244 hasAuthorship W2000183244A5079069712 @default.
• W2000183244 hasConcept C139066938 @default.
• W2000183244 hasConcept C161790260 @default.
• W2000183244 hasConcept C178790620 @default.
• W2000183244 hasConcept C179104552 @default.
• W2000183244 hasConcept C184651966 @default.
• W2000183244 hasConcept C185592680 @default.
• W2000183244 hasConcept C186927785 @default.
• W2000183244 hasConcept C44578547 @default.
• W2000183244 hasConcept C515602321 @default.
• W2000183244 hasConcept C75473681 @default.
• W2000183244 hasConcept C8010536 @default.
• W2000183244 hasConceptScore W2000183244C139066938 @default.
• W2000183244 hasConceptScore W2000183244C161790260 @default.
• W2000183244 hasConceptScore W2000183244C178790620 @default.
• W2000183244 hasConceptScore W2000183244C179104552 @default.
• W2000183244 hasConceptScore W2000183244C184651966 @default.
• W2000183244 hasConceptScore W2000183244C185592680 @default.
• W2000183244 hasConceptScore W2000183244C186927785 @default.
• W2000183244 hasConceptScore W2000183244C44578547 @default.
• W2000183244 hasConceptScore W2000183244C515602321 @default.
• W2000183244 hasConceptScore W2000183244C75473681 @default.
• W2000183244 hasConceptScore W2000183244C8010536 @default.
• W2000183244 hasIssue "1" @default.
• W2000183244 hasLocation W20001832441 @default.
• W2000183244 hasLocation W20001832442 @default.
• W2000183244 hasOpenAccess W2000183244 @default.
• W2000183244 hasPrimaryLocation W20001832441 @default.
• W2000183244 hasRelatedWork W1757607567 @default.
• W2000183244 hasRelatedWork W1964538283 @default.
• W2000183244 hasRelatedWork W1992012024 @default.
• W2000183244 hasRelatedWork W2006721870 @default.
• W2000183244 hasRelatedWork W2014815667 @default.
• W2000183244 hasRelatedWork W2070025743 @default.
• W2000183244 hasRelatedWork W2073912255 @default.
• W2000183244 hasRelatedWork W2167894278 @default.
• W2000183244 hasRelatedWork W2761433189 @default.
• W2000183244 hasRelatedWork W3137173382 @default.
• W2000183244 hasVolume "372" @default.
• W2000183244 isParatext "false" @default.
• W2000183244 isRetracted "false" @default.
• W2000183244 magId "2000183244" @default.
• W2000183244 workType "article" @default.