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- W2000201196 abstract "KIE events: Hydroxylations of fatty acids by cytochrome P450 119 Compound I display no intermolecular kinetic isotope effect (KIE) in buffer and increase in rate with increasing chain length (see graph). With glycerol, the rate of reaction of lauric acid increases, and the KIE is revealed. The mechanism involves reversible formation of an unreactive complex of a fatty acid with Compound I and its isomerization to a reactive one." @default.
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- W2000201196 date "2012-02-01" @default.
- W2000201196 modified "2023-10-18" @default.
- W2000201196 title "Rate-Controlling Isomerizations in Fatty Acid Oxidations by a Cytochrome P450 Compound I" @default.
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- W2000201196 doi "https://doi.org/10.1002/chem.201103170" @default.
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