Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000201304> ?p ?o ?g. }
- W2000201304 endingPage "5505" @default.
- W2000201304 startingPage "5499" @default.
- W2000201304 abstract "Mimicking the fundamental processes of the photosynthetic reaction center is a large field of research over the past decade. We present as biomimetic model systems for electron transfer the mono- and heteroleptic ruthenium complexes 2−9 containing differently substituted bipyridazine−glycol ligands. Depending on the number of glycol chains of the complexes 2−9, they are divided into three classes: A (2 branches, 2−4); B (3 branches, 5−6) and C (6 branches, 7−9). UV, fluorescence, single-photon counting, and laser flash photolysis were employed as techniques for photophysical characterization. Redox properties were determined using cyclic voltammetry. Detailed steady-state quenching studies of 2−9 with MV2+, OV2+, and MPVS have shown different supramolecular interactions between sensitizer and acceptor in the case of MV2+. These effects may be explained by π−π donor−acceptor attractions as well as hydrophobic interactions. Supporting molecular modeling studies have been done. The suitability as biomimetic model systems was shown by testing the ruthenium complexes 2−9 in artificial photosynthesis systems. Two typical reactions were selected: the sacrificial reduction of water and the reduction of CO2 to CH4. The use of 2−9 leads to satisfactory hydrogen production from the reduction of water. In the CH4/CO2 system, complexes 7−9 worked efficiently." @default.
- W2000201304 created "2016-06-24" @default.
- W2000201304 creator A5007001298 @default.
- W2000201304 creator A5040720263 @default.
- W2000201304 creator A5041366419 @default.
- W2000201304 creator A5044054388 @default.
- W2000201304 date "1998-03-26" @default.
- W2000201304 modified "2023-10-18" @default.
- W2000201304 title "Biomimetic Models of the Photosynthetic Reaction Center Based on Ruthenium−Polypyridine Complexes" @default.
- W2000201304 cites W1969828804 @default.
- W2000201304 cites W1970393749 @default.
- W2000201304 cites W1979129222 @default.
- W2000201304 cites W1980555929 @default.
- W2000201304 cites W1984015857 @default.
- W2000201304 cites W1987103841 @default.
- W2000201304 cites W1987981402 @default.
- W2000201304 cites W1991018449 @default.
- W2000201304 cites W1991127918 @default.
- W2000201304 cites W1992571596 @default.
- W2000201304 cites W1997960812 @default.
- W2000201304 cites W2003875395 @default.
- W2000201304 cites W2024556484 @default.
- W2000201304 cites W2026747734 @default.
- W2000201304 cites W2028110291 @default.
- W2000201304 cites W2029598432 @default.
- W2000201304 cites W2030153354 @default.
- W2000201304 cites W2034430378 @default.
- W2000201304 cites W2036374614 @default.
- W2000201304 cites W2043590726 @default.
- W2000201304 cites W2047767435 @default.
- W2000201304 cites W2049035340 @default.
- W2000201304 cites W2049745418 @default.
- W2000201304 cites W2059610498 @default.
- W2000201304 cites W2062109666 @default.
- W2000201304 cites W2074581090 @default.
- W2000201304 cites W2074861308 @default.
- W2000201304 cites W2076207935 @default.
- W2000201304 cites W2081620905 @default.
- W2000201304 cites W2081939014 @default.
- W2000201304 cites W2084648225 @default.
- W2000201304 cites W2090765324 @default.
- W2000201304 cites W2094764132 @default.
- W2000201304 cites W2101112491 @default.
- W2000201304 cites W2112565604 @default.
- W2000201304 cites W2115029038 @default.
- W2000201304 cites W2124102074 @default.
- W2000201304 cites W2134084405 @default.
- W2000201304 cites W2145773666 @default.
- W2000201304 cites W2147643258 @default.
- W2000201304 cites W2160316077 @default.
- W2000201304 cites W2205643310 @default.
- W2000201304 cites W2950168003 @default.
- W2000201304 cites W3004794190 @default.
- W2000201304 cites W77753963 @default.
- W2000201304 doi "https://doi.org/10.1021/jp9800620" @default.
- W2000201304 hasPublicationYear "1998" @default.
- W2000201304 type Work @default.
- W2000201304 sameAs 2000201304 @default.
- W2000201304 citedByCount "11" @default.
- W2000201304 crossrefType "journal-article" @default.
- W2000201304 hasAuthorship W2000201304A5007001298 @default.
- W2000201304 hasAuthorship W2000201304A5040720263 @default.
- W2000201304 hasAuthorship W2000201304A5041366419 @default.
- W2000201304 hasAuthorship W2000201304A5044054388 @default.
- W2000201304 hasConcept C121332964 @default.
- W2000201304 hasConcept C121745418 @default.
- W2000201304 hasConcept C123669783 @default.
- W2000201304 hasConcept C13472781 @default.
- W2000201304 hasConcept C147789679 @default.
- W2000201304 hasConcept C148898269 @default.
- W2000201304 hasConcept C161790260 @default.
- W2000201304 hasConcept C17525397 @default.
- W2000201304 hasConcept C178790620 @default.
- W2000201304 hasConcept C185592680 @default.
- W2000201304 hasConcept C188231169 @default.
- W2000201304 hasConcept C26873012 @default.
- W2000201304 hasConcept C2777869211 @default.
- W2000201304 hasConcept C2779892579 @default.
- W2000201304 hasConcept C2900893 @default.
- W2000201304 hasConcept C32909587 @default.
- W2000201304 hasConcept C52859227 @default.
- W2000201304 hasConcept C555196967 @default.
- W2000201304 hasConcept C55904794 @default.
- W2000201304 hasConcept C62520636 @default.
- W2000201304 hasConcept C65165184 @default.
- W2000201304 hasConcept C75473681 @default.
- W2000201304 hasConcept C87803896 @default.
- W2000201304 hasConcept C91881484 @default.
- W2000201304 hasConcept C93275456 @default.
- W2000201304 hasConcept C93391505 @default.
- W2000201304 hasConceptScore W2000201304C121332964 @default.
- W2000201304 hasConceptScore W2000201304C121745418 @default.
- W2000201304 hasConceptScore W2000201304C123669783 @default.
- W2000201304 hasConceptScore W2000201304C13472781 @default.
- W2000201304 hasConceptScore W2000201304C147789679 @default.
- W2000201304 hasConceptScore W2000201304C148898269 @default.
- W2000201304 hasConceptScore W2000201304C161790260 @default.
- W2000201304 hasConceptScore W2000201304C17525397 @default.