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- W2000204524 abstract "Azocrown ethers with sulphur atoms and pyrrole or imidazole residue as a part of macrocycle have been synthesised. Their metal complexation abilities in acetonitrile were studied using UV–vis spectrophotometry. The largest spectral changes were observed for both pyrrole- and imidazole-azothiacrown ethers on complexation with Pb2 + , Cu2 + , Zn2 + , Ni2 + , Co2 + and Ag+ ions. In the case of alkali and alkaline earth metal ions no spectral changes were found. Preliminary studies of ion-selective membrane electrodes with synthesised ionophores are presented. In the measurement for transition/heavy metal cations, only copper and lead give high responses. X-ray structure of 18-membered pyrrole azothiacrown ether is described." @default.
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- W2000204524 date "2008-10-01" @default.
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- W2000204524 title "Chromogenic azole diazothiacrown ethers" @default.
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- W2000204524 doi "https://doi.org/10.1080/10610270701666000" @default.
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