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• W2000205300 abstract "Abstract The phase separation of the aqueous solutions of cationic-anionic surfactants, C8H17 (OC2H4)nSO4NaC8H17N(CH3)3Br (C8EnSC8NM3: n = 0, 1, 3), C8SC8H17 (OC2H4)3N(CH3)3Cl (C8E3NM3), C8E3SCmH2m+1 N(CH3)3Br (CmNM3; m = 10, 12), C12H25(OC2H4)nSO4NaC12H25N(CH3)3Br (C12EnSC12NM3: n = 0, 3, 5, 7) and C8H17C6H4 (OC2H4)9,8SO4Na(C8ΦE9,8S)CmNM3 (m = 12, 14, 16) has been investigated. The concentration region of phase separation (CRPS) of the aqueous solution of C8EnSC8NM3 and C12EnSC12NM3 contracts with the increase in n, and the CRPS disappears when n is equal to (or over 3) for C8EnSC8NM3 and 7 for C12EnSC12NM3. On the contrary, the CRPS of the aqueous solution of C8E8SCmNM3, increases with the increase in m. The comparison between the molecular interaction parameter and the CRPS of the mixed system shows that the greater the molecular interaction between the two surfactant components, the easier it is for phase separation to occur, and vice versa. In the C8ΦE9,8SCmNM3 system, there is no phase separation even if m is very large. The surface activity of a 1:1 C8ΦE9,8SCmNM3 mixture is still much higher than that of the single components. A relatively large number of oxyethylene (EO) groups introduced into the cationic-anionic surfactant molecule makes the mixed aqueous solution homogeneous at a very high concentration, which is of great significance in theory and practice." @default.
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• W2000205300 date "1995-03-01" @default.
• W2000205300 modified "2023-10-04" @default.
• W2000205300 title "Phase separation of the aqueous solution and the surface activity of oxyethylenated cationic-anionic surfactants" @default.
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• W2000205300 doi "https://doi.org/10.1016/0927-7757(94)03017-t" @default.
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