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• W2000209600 endingPage "298" @default.
• W2000209600 startingPage "292" @default.
• W2000209600 abstract "The surface tensions of pure fluids (carbon dioxide, hydrogen sulfide and water) and binary systems containing (CO2 + H2O) and (H2S + H2O) are modeled by using a reliable theory. The gradient theory (GT) is combined with the simplified Perturbed-Chain Statistical Association Fluid Theory equation of state (sPC–SAFT EOS) to describe the densities and surface tensions of (CO2 + H2O) and (H2S + H2O) systems at temperature range (298.15–398.15 K) and pressure range (0.1–60 MPa). A new influence parameter in terms of bulk phase's densities is also proposed. First, the influence parameters of pure components are determined. Then, the binary interaction parameters of (CO2 + H2O) and (H2S + H2O) systems are fitted according to the bulk densities and surface tensions. Subsequently, the density profiles of the interface are determined. The surface tensions reproduced by the present model are in a good agreement with experimental data (overall AAD ~5.83 and 7.50 for constant and new proposed influence parameters, respectively)." @default.
• W2000209600 created "2016-06-24" @default.
• W2000209600 creator A5015667612 @default.
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• W2000209600 date "2014-10-01" @default.
• W2000209600 modified "2023-09-27" @default.
• W2000209600 title "Modeling the surface tension and surface properties of (CO2+H2O) and (H2S+H2O) with gradient theory in combination with sPC–SAFT EOS and a new proposed influence parameter" @default.
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• W2000209600 doi "https://doi.org/10.1016/j.molliq.2014.07.017" @default.
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