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- W2000211632 abstract "The thermal conductivity coefficient κ(T) is measured under equilibrium vapor pressure for two crystalline phases of pure methanol (orientationally ordered and orientationally disordered) at temperatures from 2K to the melting temperature Tm and also for a CH3OH+6.6% H2O glass from 2K to the glass transition temperature Tg and in the supercooled liquid from Tg to 120K. The dependence κ(T) is described approximately as a sum of two contributions: κI(T), describing heat transport by acoustic phonons, and κII(T)—by localized high-frequency excitations. The temperature dependences of the thermal conductivity of primary monoatomic alcohols CH3OH, C2H5OH, and C3H7OH in the glass state are compared. Different mechanisms of phonon scattering in the crystalline phases and glass are analyzed. The κII(T) contribution is calculated within the Cahill–Pohl model. There is an anomaly of the thermal conductivity of the glass state near Tg (a smeared minimum on the κ(T) curve)." @default.
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- W2000211632 date "2009-04-01" @default.
- W2000211632 modified "2023-09-23" @default.
- W2000211632 title "Heat transfer in solid methyl alcohol" @default.
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- W2000211632 doi "https://doi.org/10.1063/1.3115810" @default.
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