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• W2000221294 abstract "The apparatus presented in this paper is able to simultaneously confine all the atoms injected into the atomizer within the optical beam. As a consequence, during the time interval fulfilling this condition, the absorbance is constant. Experimental absorbance vs time curves, with Cd as analyte, show a constant value for more than 0.2 s. The curve shapes are in agreement with those theoretically derived for pure diffusion. This finding should lead to a method for absolute analysis that is more accurate than the methods used in ETA-AAS up to now. In fact, with this approach, one has to measure a constant signal while in the case of area measurements one has to integrate a signal that exponentially decays toward the baseline value. Data presented in this paper refer to the most volatile elements (Cd, Hg and Pb) in simple matrices. The possibility of extending the presented method to complex matrices and less volatile elements is dependent on the availability of both a more powerful power supply system and well-suited atomizer design." @default.
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• W2000221294 date "1993-04-01" @default.
• W2000221294 modified "2023-09-24" @default.
• W2000221294 title "Absolute analysis in electrothermal atomization atomic absorption spectroscopy—an atomization system for confining all the atoms injected in the opti" @default.
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• W2000221294 doi "https://doi.org/10.1016/0584-8547(93)80072-3" @default.
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