Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000222754> ?p ?o ?g. }
Showing items 1 to 74 of
74
with 100 items per page.
- W2000222754 endingPage "338" @default.
- W2000222754 startingPage "331" @default.
- W2000222754 abstract "The brominated surfactants sodium-10,11-dibromoundecanoate (6), sodium-9,10-dibromostearate (7) and sodium-9,10,12,13-tetrabromostearate (8) were synthesized and dissolved in water for the preparation of micellar solutions. Critical micelle concentrations of 50, 24 and 0.2 mM were derived from surface tension measurements for 6, 7 and sodium undecanoate respectively. When 5,5-diphenyl-1,3-cyclohexadiene (DPH) (1) is solubilized in these solutions and irradiated through quartz with a high pressure mercury lamp, photoisomerization takes place leading to products originating from the excited singlet and triplet states of DPH, mainly 1,1-diphenyl-1,3,5-hexatriene (2) and trans-5,6-diphenyl-[3.1.0]-2-hexene (3) respectively. The relative yields of 3 are higher in solutions of the brominated surfactants than in those containing no heavy atoms. This intramicellar heavy atom effect is shown to be a complex phenomenon also depending on temperature and the structure of the micelles." @default.
- W2000222754 created "2016-06-24" @default.
- W2000222754 creator A5024274719 @default.
- W2000222754 creator A5037918008 @default.
- W2000222754 creator A5058629026 @default.
- W2000222754 date "1991-06-01" @default.
- W2000222754 modified "2023-09-27" @default.
- W2000222754 title "Intramicellar heavy atom effects in the photoisomerization of 5,5-diphenyl-1,3-cyclohexadiene" @default.
- W2000222754 cites W2030400319 @default.
- W2000222754 cites W2033157897 @default.
- W2000222754 cites W2040819783 @default.
- W2000222754 cites W2055242756 @default.
- W2000222754 cites W2092862449 @default.
- W2000222754 cites W2320483273 @default.
- W2000222754 doi "https://doi.org/10.1016/1010-6030(91)87052-w" @default.
- W2000222754 hasPublicationYear "1991" @default.
- W2000222754 type Work @default.
- W2000222754 sameAs 2000222754 @default.
- W2000222754 citedByCount "3" @default.
- W2000222754 crossrefType "journal-article" @default.
- W2000222754 hasAuthorship W2000222754A5024274719 @default.
- W2000222754 hasAuthorship W2000222754A5037918008 @default.
- W2000222754 hasAuthorship W2000222754A5058629026 @default.
- W2000222754 hasConcept C111337013 @default.
- W2000222754 hasConcept C11268172 @default.
- W2000222754 hasConcept C121332964 @default.
- W2000222754 hasConcept C126661725 @default.
- W2000222754 hasConcept C161790260 @default.
- W2000222754 hasConcept C178790620 @default.
- W2000222754 hasConcept C181500209 @default.
- W2000222754 hasConcept C184651966 @default.
- W2000222754 hasConcept C185544564 @default.
- W2000222754 hasConcept C185592680 @default.
- W2000222754 hasConcept C33062035 @default.
- W2000222754 hasConcept C537181965 @default.
- W2000222754 hasConcept C64237528 @default.
- W2000222754 hasConcept C75473681 @default.
- W2000222754 hasConcept C85311670 @default.
- W2000222754 hasConceptScore W2000222754C111337013 @default.
- W2000222754 hasConceptScore W2000222754C11268172 @default.
- W2000222754 hasConceptScore W2000222754C121332964 @default.
- W2000222754 hasConceptScore W2000222754C126661725 @default.
- W2000222754 hasConceptScore W2000222754C161790260 @default.
- W2000222754 hasConceptScore W2000222754C178790620 @default.
- W2000222754 hasConceptScore W2000222754C181500209 @default.
- W2000222754 hasConceptScore W2000222754C184651966 @default.
- W2000222754 hasConceptScore W2000222754C185544564 @default.
- W2000222754 hasConceptScore W2000222754C185592680 @default.
- W2000222754 hasConceptScore W2000222754C33062035 @default.
- W2000222754 hasConceptScore W2000222754C537181965 @default.
- W2000222754 hasConceptScore W2000222754C64237528 @default.
- W2000222754 hasConceptScore W2000222754C75473681 @default.
- W2000222754 hasConceptScore W2000222754C85311670 @default.
- W2000222754 hasIssue "3" @default.
- W2000222754 hasLocation W20002227541 @default.
- W2000222754 hasOpenAccess W2000222754 @default.
- W2000222754 hasPrimaryLocation W20002227541 @default.
- W2000222754 hasRelatedWork W1966947593 @default.
- W2000222754 hasRelatedWork W1972820942 @default.
- W2000222754 hasRelatedWork W2009706153 @default.
- W2000222754 hasRelatedWork W2019604830 @default.
- W2000222754 hasRelatedWork W2054272747 @default.
- W2000222754 hasRelatedWork W2070083433 @default.
- W2000222754 hasRelatedWork W2082953596 @default.
- W2000222754 hasRelatedWork W2091479873 @default.
- W2000222754 hasRelatedWork W4229003985 @default.
- W2000222754 hasRelatedWork W4312095237 @default.
- W2000222754 hasVolume "58" @default.
- W2000222754 isParatext "false" @default.
- W2000222754 isRetracted "false" @default.
- W2000222754 magId "2000222754" @default.
- W2000222754 workType "article" @default.