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• W2000225514 abstract "Elemental iron and zinc reduced part-per-thousand levels of aqueous-phase carbon tetrachloride to chloroform in a few hours. Free metal ions, chloride ion and hydrogen gas were produced in the reaction; protons were consumed. Process kinetics were dependent on solution pH, surface area of the elemental metal, carbon tetrachloride concentration, buffer selection and solvent composition (volume fraction 2-propanol). Reaction rate was first-order with respect to carbon tetrachloride at concentrations less than 7.5 mM. This class of reactions offers promise as a means for initiating the destruction of heavily halogenated organic compounds." @default.
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• W2000225514 date "1995-05-01" @default.
• W2000225514 modified "2023-09-23" @default.
• W2000225514 title "Kinetics and mechanism of reductive dehalogenation of carbon tetrachloride using zero-valence metals" @default.
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• W2000225514 doi "https://doi.org/10.1016/0304-3894(94)00117-y" @default.
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