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• W2000226080 endingPage "174" @default.
• W2000226080 startingPage "170" @default.
• W2000226080 abstract "The absolute rate theory expression for the rate of the internal rotation of a methyl group, or a similar internal rotor, hindered by a three-fold barrier, is developed. This expression is used to derive the activation energy and activation enthalpy for the process. Numerical calculations are performed using two assumptions regarding the form of the potential for two typical methyl barrier heights at three temperatures. The Arrhenius activation energies (Ea) are found to be nearly temperature independent in the range 200–333 K and only 2–4% lower than the barrier height values (V3). The effect of tunneling is estimated to be about 2–3%." @default.
• W2000226080 created "2016-06-24" @default.
• W2000226080 creator A5071791987 @default.
• W2000226080 creator A5091259271 @default.
• W2000226080 date "1979-06-01" @default.
• W2000226080 modified "2023-09-28" @default.
• W2000226080 title "On the relationship between the potential barrier and the activation energy for the internal rotation of a methyl group" @default.
• W2000226080 cites W2010797146 @default.
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• W2000226080 doi "https://doi.org/10.1016/0009-2614(79)87302-9" @default.
• W2000226080 hasPublicationYear "1979" @default.
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