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- W2000235154 abstract "Polystyryldilithium (PSLi2), polystyryldipotassium (PSK2) or poly(9,9-dimethyl-2-vinylfluorene)yl dipotassium (PDMVF-K2), generated by electron transfer initiated polymerizations, were reacted with 9,10-bis(chloromethyl)anthracene (BCMA) under high dilution conditions to afford 9,10-anthracenylidene labeled PS or PDMVF macrocycles. However, only potassium ion mediated coupling reactions with BCMA gave high extents of 9,10-anthracenylidene incorporation (>90%) while analogous lithium ion systems afforded no more than 50% incorporation. Coupling reactions of PSK2 with 9,10-bis(bromomethyl)anthracene (BBMA) also gave lower degrees of coupling and 9,10-anthracenylidene incorporation. Metal−halogen exchange or electron-transfer reactions may be responsible for the lower degree of 9,10-anthracenylidene labeling." @default.
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- W2000235154 date "2001-08-11" @default.
- W2000235154 modified "2023-09-24" @default.
- W2000235154 title "Synthesis of Macrocyclic Polystyrene and Macrocyclic Poly(9,9-dimethyl-2-vinylfluorene) Containing a Single 9,10-Anthracenylidene Group" @default.
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- W2000235154 doi "https://doi.org/10.1021/ma0105892" @default.
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