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- W2000235267 abstract "Abstract The synthesis and physical properties of crystalline lanthanide perchlorate di-n-buthyl sulfoxide complexes (Ln(ClO 4 ) 3 · 6Bu 2 SO, where Ln = La-Nd, Sm-Lu, and Y) are reported. The i.r. spectra, the molar electrolytic conductances in nitromethane and acetonitrile and the X-ray powder patterns of the complexes were determined. The i.r. spectra reveal that all Bu 2 SO′s are coordinated to the metal ions, oxygen being the donor atom. A partial and weak coordination of perchlorate ions to the lanthanide ions of greater radius is also evidenced by i.r. spectral data. The electronic spectra of the neodymium complex indicate different environments in solid state and in acetonitrile and nitromethane solutions." @default.
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- W2000235267 date "1976-01-01" @default.
- W2000235267 modified "2023-10-18" @default.
- W2000235267 title "Di-n-buthyl sulfoxide complexes of lanthanide perchlorates" @default.
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- W2000235267 doi "https://doi.org/10.1016/s0020-1693(00)91103-4" @default.
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