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- W2000238634 abstract "Using translationally hot H atoms generated via the photolysis of HBr at 193 nm, we have investigated the dynamics of the reaction H+D2O→OD+HD at a center-of-mass energy of Ec.m. = 2.53 eV. The nascent OD (ν=0) rotational distribution was probed by laser-induced fluorescence. We found that only a small fraction (2.3%) of the total available energy appears as rotational energy of the OD product molecule and within our detection limit no OD (ν=1) could be found. The absolute reactive cross section σR=0.11±0.02 Å2 at Ec.m. = 2.53 eV was determined by means of a calibration method and was found to be 2.4 times smaller than the reactive cross section of the reaction H+H2O→OH+H2 at a comparable center of mass energy of Ec.m.=2.52 eV." @default.
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- W2000238634 date "1992-08-01" @default.
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- W2000238634 title "Absolute reactive cross section for the reaction H+D2O→OD+HD: a comparison to the protonated case" @default.
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- W2000238634 doi "https://doi.org/10.1016/0009-2614(92)85963-b" @default.
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