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- W2000240229 abstract "Abstract Site-selective direct arylation of both sp2 and sp3 sites on azine N-oxide substrates is described. The arylation reactions are carried out in either a divergent manner or a sequential manner. The sp3 arylation reaction is applied to the synthesis of the natural products, papaverine and crykonisine, and a rationale for low reactivity of electron-deficient aryl halides is provided. Mechanistic investigations point toward the intimate involvement of the base in the mechanism of these reactions." @default.
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- W2000240229 date "2009-08-11" @default.
- W2000240229 modified "2023-09-26" @default.
- W2000240229 title "ChemInform Abstract: Catalyst and Base Controlled Site-Selective sp2and sp3Direct Arylation of Azine N-Oxides." @default.
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- W2000240229 doi "https://doi.org/10.1002/chin.200932097" @default.
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