FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000245114> ?p ?o ?g. }

• W2000245114 endingPage "2453" @default.
• W2000245114 startingPage "2444" @default.
• W2000245114 abstract "Dioxane-type (9'-anthracenyl)methylene acetal of methyl 2,3-di-O-methyl-alpha-D-glucopyranoside was cleaved with LiAlH(4)/AlCl(3) (3:1) or with Na(CN)BH(3)-HCl regioselectively to provide the 4- or 6-O-(9'-anthracenyl)methyl ether, respectively. Hydrogenolytic reaction of the exo and endo isomers of dioxolane-type acetals proved to be directed by the configuration of the acetalic carbon as well as by the intramolecular participation of the adjacent-free hydroxyl; ring-opening reaction of the endo isomer of the methyl 2,3-O-(9'-anthracenyl)methylene-alpha-L-rhamnopyranoside took place with complete selectivity resulting in the axial (9'-anthracenyl)methyl ether, whereas a 1:1 mixture of the axial and equatorial ethers was formed upon the same reaction of the exo isomer. Catalytic hydrogenation of the sugar acetals resulted in (9',10'-dihydro-9'-anthracenyl)methylene derivatives without affecting the acetalic center. High-temperature molecular dynamics simulations and DFT (Density Functional Theory) geometry optimizations were carried out to study the conformation of the dioxane-type (9',10'-dihydro-9'-anthracenyl)methylene acetal." @default.
• W2000245114 created "2016-06-24" @default.
• W2000245114 creator A5015086810 @default.
• W2000245114 creator A5015999016 @default.
• W2000245114 creator A5018308041 @default.
• W2000245114 creator A5037882556 @default.
• W2000245114 creator A5038109877 @default.
• W2000245114 creator A5046844847 @default.
• W2000245114 creator A5075323450 @default.
• W2000245114 creator A5081806586 @default.
• W2000245114 date "2009-12-01" @default.
• W2000245114 modified "2023-10-16" @default.
• W2000245114 title "Synthesis, regioselective hydrogenolysis, partial hydrogenation, and conformational study of dioxane and dioxolane-type (9′-anthracenyl)methylene acetals of sugars" @default.
• W2000245114 cites W1928150933 @default.
• W2000245114 cites W1969408239 @default.
• W2000245114 cites W1971696722 @default.
• W2000245114 cites W1982519957 @default.
• W2000245114 cites W1983514759 @default.
• W2000245114 cites W1986874205 @default.
• W2000245114 cites W2002932252 @default.
• W2000245114 cites W2014740844 @default.
• W2000245114 cites W2029667189 @default.
• W2000245114 cites W2048525214 @default.
• W2000245114 cites W2059557806 @default.
• W2000245114 cites W2063334178 @default.
• W2000245114 cites W2073207114 @default.
• W2000245114 cites W2077786169 @default.
• W2000245114 cites W2080182825 @default.
• W2000245114 cites W2085740077 @default.
• W2000245114 cites W2085952218 @default.
• W2000245114 cites W2091921527 @default.
• W2000245114 cites W2131350133 @default.
• W2000245114 cites W2171537021 @default.
• W2000245114 cites W2952926812 @default.
• W2000245114 cites W4293208197 @default.
• W2000245114 doi "https://doi.org/10.1016/j.carres.2009.09.007" @default.
• W2000245114 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19879559" @default.
• W2000245114 hasPublicationYear "2009" @default.
• W2000245114 type Work @default.
• W2000245114 sameAs 2000245114 @default.
• W2000245114 citedByCount "14" @default.
• W2000245114 countsByYear W20002451142012 @default.
• W2000245114 countsByYear W20002451142013 @default.
• W2000245114 countsByYear W20002451142014 @default.
• W2000245114 countsByYear W20002451142015 @default.
• W2000245114 countsByYear W20002451142016 @default.
• W2000245114 countsByYear W20002451142018 @default.
• W2000245114 countsByYear W20002451142021 @default.
• W2000245114 crossrefType "journal-article" @default.
• W2000245114 hasAuthorship W2000245114A5015086810 @default.
• W2000245114 hasAuthorship W2000245114A5015999016 @default.
• W2000245114 hasAuthorship W2000245114A5018308041 @default.
• W2000245114 hasAuthorship W2000245114A5037882556 @default.
• W2000245114 hasAuthorship W2000245114A5038109877 @default.
• W2000245114 hasAuthorship W2000245114A5046844847 @default.
• W2000245114 hasAuthorship W2000245114A5075323450 @default.
• W2000245114 hasAuthorship W2000245114A5081806586 @default.
• W2000245114 hasBestOaLocation W20002451142 @default.
• W2000245114 hasConcept C155647269 @default.
• W2000245114 hasConcept C161790260 @default.
• W2000245114 hasConcept C178790620 @default.
• W2000245114 hasConcept C181886296 @default.
• W2000245114 hasConcept C185592680 @default.
• W2000245114 hasConcept C2776666804 @default.
• W2000245114 hasConcept C2777454769 @default.
• W2000245114 hasConcept C2777731525 @default.
• W2000245114 hasConcept C2780407432 @default.
• W2000245114 hasConcept C59759590 @default.
• W2000245114 hasConcept C71240020 @default.
• W2000245114 hasConcept C75079739 @default.
• W2000245114 hasConceptScore W2000245114C155647269 @default.
• W2000245114 hasConceptScore W2000245114C161790260 @default.
• W2000245114 hasConceptScore W2000245114C178790620 @default.
• W2000245114 hasConceptScore W2000245114C181886296 @default.
• W2000245114 hasConceptScore W2000245114C185592680 @default.
• W2000245114 hasConceptScore W2000245114C2776666804 @default.
• W2000245114 hasConceptScore W2000245114C2777454769 @default.
• W2000245114 hasConceptScore W2000245114C2777731525 @default.
• W2000245114 hasConceptScore W2000245114C2780407432 @default.
• W2000245114 hasConceptScore W2000245114C59759590 @default.
• W2000245114 hasConceptScore W2000245114C71240020 @default.
• W2000245114 hasConceptScore W2000245114C75079739 @default.
• W2000245114 hasIssue "18" @default.
• W2000245114 hasLocation W20002451141 @default.
• W2000245114 hasLocation W20002451142 @default.
• W2000245114 hasLocation W20002451143 @default.
• W2000245114 hasOpenAccess W2000245114 @default.
• W2000245114 hasPrimaryLocation W20002451141 @default.
• W2000245114 hasRelatedWork W1972968350 @default.
• W2000245114 hasRelatedWork W2004785920 @default.
• W2000245114 hasRelatedWork W2047595023 @default.
• W2000245114 hasRelatedWork W2049094039 @default.
• W2000245114 hasRelatedWork W2053151132 @default.
• W2000245114 hasRelatedWork W2058613322 @default.
• W2000245114 hasRelatedWork W2076743626 @default.
• W2000245114 hasRelatedWork W2408963775 @default.
• W2000245114 hasRelatedWork W2951787805 @default.
• W2000245114 hasRelatedWork W4254132057 @default.

• next