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- W2000248662 abstract "The polymerization of acrylonitrile (M) initiated by the Ce(IV)–acetophenone (AP) redox pair has been studied in acetic–sulfuric acid mixtures in a nitrogen atmosphere. The rate of polymerization is proportional to [M]3/2, [AP]1/2 and [Ce(IV)]1/2. The rate of disappearance of ceric ion,–RCe, is proportional to [AP], [M], and [Ce(IV)]. The effect of certain salts, solvent, acid and temperature on both the rates have been investigated. A suitable kinetic scheme has been proposed, and the composite rate constants kp 2(k/k/t) and k0/ki are reported." @default.
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- W2000248662 date "1978-02-01" @default.
- W2000248662 modified "2023-09-26" @default.
- W2000248662 title "Vinyl polymerization: Kinetics of Ce(IV)–acetophenone-initiated polymerization of acrylonitrile in acetic–sulfuric acid mixtures" @default.
- W2000248662 doi "https://doi.org/10.1002/pol.1978.170160209" @default.
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