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- W2000249116 abstract "The crystal structures of the two chiral alkyllithium bases [n-BuLi.(-)-sparteine]2 (1) and [Et2O.(i-PrLi)2.(-)-sparteine] (2) have been determined. For compound 1, a symmetric dimer is observed in the solid state, with two (-)-sparteine ligands coordinating to the lithium centers. Because of steric reasons, compound 2 crystallizes as an unsymmetric dimer with the four methyl groups pointing away from the sterically demanding (-)-sparteine ligand. Compound 2 contains one four-coordinate lithium center [coordinated to (-)-sparteine] and one three-coordinate lithium center (coordinated to Et2O). As a result of this arrangement, significantly different Li-C distances are found in the central four-membered ring of compound 2." @default.
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- W2000249116 date "2003-10-17" @default.
- W2000249116 modified "2023-10-14" @default.
- W2000249116 title "The Crystal Structures of the Chiral Alkyllithium Bases [<i>n</i>-BuLi·(−)-Sparteine]<sub>2</sub> and [Et<sub>2</sub>O·(<i>i</i>-PrLi)<sub>2</sub>·(−)-Sparteine]" @default.
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- W2000249116 doi "https://doi.org/10.1021/ja0374372" @default.
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