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• W2000249928 abstract "Six isotypic R6ZTe2 phases have been synthesized in Ta at elevated temperatures and characterized by single crystal X-ray refinements for R=Y, Z=Rh, Pd, Ag, Y and for R=Lu, Z=Cu, Ag. All crystallize in the Sc6PdTe2-type structure, Pnma, Z=4, a∼21.5 Å, b∼4.1 Å, c∼11.4 Å. The results can be viewed as the replacement of Te3 atoms in the parent isotypic Sc2Te (or in the hypothetical Y2Te or Lu2Te analogues) by the above the Z, the Y example giving the new binary phase Y7Te2. The shorter (and stronger) metal-metal bonds concentrate in the region of metal (Z, Y) substitution, as revealed by larger integrated crystal orbital Hamilton population (ICOHP) values derived from linear muffin-tin-orbital (LMTO) calculations. Partial densities-of-states data for Y7Te2 reflect a similar behavior. Individual R–R bond distances are seen to deviate appreciably from the more fundamental overlap population measures for each." @default.
• W2000249928 created "2016-06-24" @default.
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• W2000249928 date "2007-11-01" @default.
• W2000249928 modified "2023-09-24" @default.
• W2000249928 title "Condensed rare-earth metal-rich tellurides. Extension of layered Sc6PdTe2-type compounds to yttrium and lutetium analogues and to Y7Te2, the limiting binary member" @default.
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• W2000249928 doi "https://doi.org/10.1016/j.jssc.2007.09.012" @default.
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