FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000249936> ?p ?o ?g. }

• W2000249936 endingPage "1472" @default.
• W2000249936 startingPage "1467" @default.
• W2000249936 abstract "The adsorption of carbon monoxide on the MgO(100) surface, prepared in situ by cleaving a single crystal in ultra high vacuum, has been studied at temperatures between 32 and 56 K using polarization Fourier transform infrared spectroscopy. Above 45 K a single IR absorption at 2150.5 cm−1 is detected with p-polarization only which indicates a dynamic CO dipole perpendicular to the surface. Below 45 K the spectra of the monolayer are completely different. Using p-polarization the main IR absorption is detected at 2151.2 cm−1. Two additional features are observed at 2137.2 and at 2132.5 cm−1, only the latter is also observed with s-polarization. The spectrum indicates an ordered monolayer with two energetically different adsorption sites per unit cell. A c(4 × 2) symmetry is inferred in concert with helium atom scattering [Gerlach et al., Surf. Sci. 331–333 (1995) 1490]; from LEED [Audibert et al., Surf. Sci. 273(1992) L467; Panella et al., J. Phys. Paris 4 (1994) 905] a (4 × 2) symmetry was derived. The p-polarized absorption at 2151.2 cm−1 is assigned to a dynamic CO dipole perpendicular to the surface, the doublet is attributed to the in-phase and the out-of-phase vibrational exciton of two tilted CO molecules at energetically equivalent sites. Their projections on the surface are oriented antiparallel, the dipole of the in-phase exciton at 2137.2 cm−1 is perpendicular to the surface and has no azimuthal component, the dipole of the out-of-phase exciton at 2132.5 cm−1 is parallel to the surface. A weak prevalence of one domain is inferred from the spectra." @default.
• W2000249936 created "2016-06-24" @default.
• W2000249936 creator A5049923612 @default.
• W2000249936 creator A5051973734 @default.
• W2000249936 creator A5071842373 @default.
• W2000249936 creator A5087551423 @default.
• W2000249936 date "1995-07-01" @default.
• W2000249936 modified "2023-10-11" @default.
• W2000249936 title "The monolayer CO adsorbed on MgO(100) detected by polarization infrared spectroscopy" @default.
• W2000249936 cites W1676840954 @default.
• W2000249936 cites W1971943685 @default.
• W2000249936 cites W1974254403 @default.
• W2000249936 cites W1986164670 @default.
• W2000249936 cites W2005458784 @default.
• W2000249936 cites W2012438843 @default.
• W2000249936 cites W2024276519 @default.
• W2000249936 cites W2033014123 @default.
• W2000249936 cites W2034166786 @default.
• W2000249936 cites W2053968362 @default.
• W2000249936 cites W2072677970 @default.
• W2000249936 cites W2080293593 @default.
• W2000249936 cites W2086388745 @default.
• W2000249936 cites W2117591807 @default.
• W2000249936 cites W2169650457 @default.
• W2000249936 doi "https://doi.org/10.1016/0039-6028(95)00223-5" @default.
• W2000249936 hasPublicationYear "1995" @default.
• W2000249936 type Work @default.
• W2000249936 sameAs 2000249936 @default.
• W2000249936 citedByCount "57" @default.
• W2000249936 countsByYear W20002499362012 @default.
• W2000249936 countsByYear W20002499362013 @default.
• W2000249936 countsByYear W20002499362014 @default.
• W2000249936 countsByYear W20002499362015 @default.
• W2000249936 countsByYear W20002499362017 @default.
• W2000249936 countsByYear W20002499362018 @default.
• W2000249936 countsByYear W20002499362019 @default.
• W2000249936 countsByYear W20002499362020 @default.
• W2000249936 countsByYear W20002499362021 @default.
• W2000249936 crossrefType "journal-article" @default.
• W2000249936 hasAuthorship W2000249936A5049923612 @default.
• W2000249936 hasAuthorship W2000249936A5051973734 @default.
• W2000249936 hasAuthorship W2000249936A5071842373 @default.
• W2000249936 hasAuthorship W2000249936A5087551423 @default.
• W2000249936 hasConcept C113196181 @default.
• W2000249936 hasConcept C119824511 @default.
• W2000249936 hasConcept C120665830 @default.
• W2000249936 hasConcept C121332964 @default.
• W2000249936 hasConcept C147789679 @default.
• W2000249936 hasConcept C153642686 @default.
• W2000249936 hasConcept C158355884 @default.
• W2000249936 hasConcept C173523689 @default.
• W2000249936 hasConcept C178790620 @default.
• W2000249936 hasConcept C184779094 @default.
• W2000249936 hasConcept C185592680 @default.
• W2000249936 hasConcept C191486275 @default.
• W2000249936 hasConcept C192562407 @default.
• W2000249936 hasConcept C205049153 @default.
• W2000249936 hasConcept C32891209 @default.
• W2000249936 hasConcept C41999313 @default.
• W2000249936 hasConcept C43617362 @default.
• W2000249936 hasConcept C55493867 @default.
• W2000249936 hasConcept C62520636 @default.
• W2000249936 hasConcept C7070889 @default.
• W2000249936 hasConceptScore W2000249936C113196181 @default.
• W2000249936 hasConceptScore W2000249936C119824511 @default.
• W2000249936 hasConceptScore W2000249936C120665830 @default.
• W2000249936 hasConceptScore W2000249936C121332964 @default.
• W2000249936 hasConceptScore W2000249936C147789679 @default.
• W2000249936 hasConceptScore W2000249936C153642686 @default.
• W2000249936 hasConceptScore W2000249936C158355884 @default.
• W2000249936 hasConceptScore W2000249936C173523689 @default.
• W2000249936 hasConceptScore W2000249936C178790620 @default.
• W2000249936 hasConceptScore W2000249936C184779094 @default.
• W2000249936 hasConceptScore W2000249936C185592680 @default.
• W2000249936 hasConceptScore W2000249936C191486275 @default.
• W2000249936 hasConceptScore W2000249936C192562407 @default.
• W2000249936 hasConceptScore W2000249936C205049153 @default.
• W2000249936 hasConceptScore W2000249936C32891209 @default.
• W2000249936 hasConceptScore W2000249936C41999313 @default.
• W2000249936 hasConceptScore W2000249936C43617362 @default.
• W2000249936 hasConceptScore W2000249936C55493867 @default.
• W2000249936 hasConceptScore W2000249936C62520636 @default.
• W2000249936 hasConceptScore W2000249936C7070889 @default.
• W2000249936 hasLocation W20002499361 @default.
• W2000249936 hasOpenAccess W2000249936 @default.
• W2000249936 hasPrimaryLocation W20002499361 @default.
• W2000249936 hasRelatedWork W117824151 @default.
• W2000249936 hasRelatedWork W1982027788 @default.
• W2000249936 hasRelatedWork W2008512696 @default.
• W2000249936 hasRelatedWork W2018674345 @default.
• W2000249936 hasRelatedWork W2135375667 @default.
• W2000249936 hasRelatedWork W2469340274 @default.
• W2000249936 hasRelatedWork W2490963019 @default.
• W2000249936 hasRelatedWork W2916853706 @default.
• W2000249936 hasRelatedWork W4236933654 @default.
• W2000249936 hasRelatedWork W4323652357 @default.
• W2000249936 hasVolume "331-333" @default.
• W2000249936 isParatext "false" @default.

• next