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• W2000253140 abstract "In the presence of dimethylzinc, (R)-tert-butyldimethylsiloxy-2-cyclopentenone can be linked with (S,E)-1-lithio-3-tert-butyldimethylsiloxy-1-octene and methyl 7-1odo-5-heptynoate, giving a protected 5,6didehydroprostaglandin E2- Use of an ω side-chain aldehyde or nitroalkene in place of the propargylic iodide affords the C-7 and C-6 functionalized prostaglandins, respectively. This new protocol constitutes the simplest three-component method for the synthesis of various natural and unnatural prostaglandins." @default.
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• W2000253140 date "1990-01-01" @default.
• W2000253140 modified "2023-10-16" @default.
• W2000253140 title "Three-component coupling synthesis of prostaglandins. A simplified, general procedure" @default.
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• W2000253140 doi "https://doi.org/10.1016/s0040-4020(01)85596-4" @default.
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