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- W2000255183 abstract "The kinetics of anation reactions of trans-Rh en2L(OH2)2+ with X–(L and X = Cl, Br, or I) have been studied and rate parameters obtained. Combination of these parameters with thermodynamic and kinetic parameters obtained previously enables the relative stabilities of the dihalogeno-complexes and their corresponding aquohalogeno-complexes to be calculated. Values for the relative enthalpies of the aquochloro-, aquobromo-, and aquoiodo-complexes in aqueous solution have also been calculated, and the results show that H2O is a “harder” ligand than chloride. The kinetic trans-effect of L on the Rh–OH2, bond is I > Br > Cl. Comparison with data for the trans-effect on rhodium–halide bonds shows that the magnitude of the trans-effect increases with increasing “hardness” of the leaving group." @default.
- W2000255183 created "2016-06-24" @default.
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- W2000255183 date "1967-01-01" @default.
- W2000255183 modified "2023-09-27" @default.
- W2000255183 title "The trans-effect in octahedral complexes. Part II. Anation reactions of some trans-Rh en<sub>2</sub>L(OH<sub>2</sub>)<sup>2+</sup>complexes" @default.
- W2000255183 doi "https://doi.org/10.1039/j19670000205" @default.
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