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- W2000255746 abstract "Hydrogen is transferred from acridane (1c) and N-methylacridane (1d) to α-methyl-styrene (2) in a bimolecular uncatalyzed reaction at 260–300°C. On the basis of the activation parameters (for 1c: ΔH≠ = 29.0 kcal/mol, ΔS≠ = −23.5 e.u. in triglyme) the kinetic isotope effect (kH/kD = 2.0, in triglyme at 300°C) as well as the small solvent effects and from the observation of an EPR signal of N-methylhydroacridyl radicals a three-step radical mechanism is prosposed which is initiated by a retrodisproportionation between 1 and 2." @default.
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- W2000255746 date "1995-07-01" @default.
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- W2000255746 title "Bimolecular formation of radicals by hydrogen transfer, 9. Uncatalyzed transfer hydrogenation of α-methylstyrene by 9,10-dihydroacridine andN-methyl-9,10-dihydroacridine" @default.
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- W2000255746 doi "https://doi.org/10.1002/jlac.1995199507177" @default.
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