FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000257039> ?p ?o ?g. }

• W2000257039 endingPage "1857" @default.
• W2000257039 startingPage "1849" @default.
• W2000257039 abstract "A very detailed ligand-field (LF) model is developed to account for the increase of one or two orders of magnitude of the spin-lattice coupling coefficients (SLCC) of ${mathrm{Mn}}^{2+}$ in the common cation series ZnS, ZnSe, ZnTe, and CdTe. First, an overall LF model shows that the SLCC's are correctly given for all studied compounds by a second-order perturbation scheme involving twice the molecular spin-orbit interaction acting between the fundamental state $^{6}$${mathit{A}}_{1}$ and the three excited states $^{4}$${mathit{T}}_{1}$ at lower energy. This model gives the contributions to the SLCC's of the strain-induced variations of the electrostatic field of the crystal, of the ligand-ligand and metal-ligand group overlaps, and of the molecular spin-orbit interaction. Second, a new analysis of the LF model gives the strain-induced variations of the splitting of the states $^{4}$${mathit{T}}_{1}$, of the monoelectronic molecular wave functions, and of the orbital operator of the molecular spin-orbit interaction. Finally, by expressing the SLCC's as a linear combination of quadratic terms in the spin-orbit constants ${mathrm{ensuremath{zeta}}}_{mathit{M}}$ of the electrons d of the metal and ${mathrm{ensuremath{zeta}}}_{mathit{L}}$ of the electrons p of the ligands and bilinear terms in ${mathrm{ensuremath{zeta}}}_{mathit{M}}$${mathrm{ensuremath{zeta}}}_{mathit{L}}$, it is shown that the terms in ${mathrm{ensuremath{zeta}}}_{mathit{M}}^{2}$ are approximately identical for all compounds, while the terms in ${mathrm{ensuremath{zeta}}}_{mathit{M}}$${mathrm{ensuremath{zeta}}}_{mathit{L}}$ which are partly compensated by the terms in ${mathrm{ensuremath{zeta}}}_{mathit{L}}^{2}$ become preponderant when passing from ZnS to ZnSe, ZnTe, and CdTe. These results account for the observed roughly linear dependence of the SLCC's on ${mathrm{ensuremath{zeta}}}_{mathit{L}}$ for the common cation series ZnS, ZnSe, and ZnTe and show that molecular spin-orbit interaction is essential to analyze spin-orbit-dependent spectroscopic constants when the ratio ${mathrm{ensuremath{zeta}}}_{mathit{L}}$/${mathrm{ensuremath{zeta}}}_{mathit{M}}$ is greater than unity." @default.
• W2000257039 created "2016-06-24" @default.
• W2000257039 creator A5013068848 @default.
• W2000257039 creator A5069200807 @default.
• W2000257039 date "1993-01-15" @default.
• W2000257039 modified "2023-10-02" @default.
• W2000257039 title "Molecular spin-orbit interaction ford5ions in covalent crystals: Spin-lattice coupling coefficients ofMn2+in II-VI compounds" @default.
• W2000257039 cites W1971238203 @default.
• W2000257039 cites W1973384236 @default.
• W2000257039 cites W1977527861 @default.
• W2000257039 cites W1977820423 @default.
• W2000257039 cites W1981922770 @default.
• W2000257039 cites W1984110164 @default.
• W2000257039 cites W1985014914 @default.
• W2000257039 cites W1986647117 @default.
• W2000257039 cites W1989341892 @default.
• W2000257039 cites W1991057929 @default.
• W2000257039 cites W1996535727 @default.
• W2000257039 cites W2008158244 @default.
• W2000257039 cites W2011164966 @default.
• W2000257039 cites W2029109639 @default.
• W2000257039 cites W2037373967 @default.
• W2000257039 cites W2038487951 @default.
• W2000257039 cites W2043743546 @default.
• W2000257039 cites W2051208788 @default.
• W2000257039 cites W2051957633 @default.
• W2000257039 cites W2054864781 @default.
• W2000257039 cites W2057123608 @default.
• W2000257039 cites W2058768367 @default.
• W2000257039 cites W2061062730 @default.
• W2000257039 cites W2061558561 @default.
• W2000257039 cites W2064721123 @default.
• W2000257039 cites W2067981174 @default.
• W2000257039 cites W2075772418 @default.
• W2000257039 cites W2090555827 @default.
• W2000257039 cites W2138633773 @default.
• W2000257039 cites W2322372201 @default.
• W2000257039 cites W2607690156 @default.
• W2000257039 cites W2737271828 @default.
• W2000257039 doi "https://doi.org/10.1103/physrevb.47.1849" @default.
• W2000257039 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10006222" @default.
• W2000257039 hasPublicationYear "1993" @default.
• W2000257039 type Work @default.
• W2000257039 sameAs 2000257039 @default.
• W2000257039 citedByCount "12" @default.
• W2000257039 countsByYear W20002570392012 @default.
• W2000257039 countsByYear W20002570392014 @default.
• W2000257039 countsByYear W20002570392017 @default.
• W2000257039 countsByYear W20002570392021 @default.
• W2000257039 crossrefType "journal-article" @default.
• W2000257039 hasAuthorship W2000257039A5013068848 @default.
• W2000257039 hasAuthorship W2000257039A5069200807 @default.
• W2000257039 hasConcept C121332964 @default.
• W2000257039 hasConcept C125020911 @default.
• W2000257039 hasConcept C145148216 @default.
• W2000257039 hasConcept C181500209 @default.
• W2000257039 hasConcept C184779094 @default.
• W2000257039 hasConcept C185592680 @default.
• W2000257039 hasConcept C24890656 @default.
• W2000257039 hasConcept C26873012 @default.
• W2000257039 hasConcept C2781204021 @default.
• W2000257039 hasConcept C57805442 @default.
• W2000257039 hasConcept C62520636 @default.
• W2000257039 hasConcept C8010536 @default.
• W2000257039 hasConceptScore W2000257039C121332964 @default.
• W2000257039 hasConceptScore W2000257039C125020911 @default.
• W2000257039 hasConceptScore W2000257039C145148216 @default.
• W2000257039 hasConceptScore W2000257039C181500209 @default.
• W2000257039 hasConceptScore W2000257039C184779094 @default.
• W2000257039 hasConceptScore W2000257039C185592680 @default.
• W2000257039 hasConceptScore W2000257039C24890656 @default.
• W2000257039 hasConceptScore W2000257039C26873012 @default.
• W2000257039 hasConceptScore W2000257039C2781204021 @default.
• W2000257039 hasConceptScore W2000257039C57805442 @default.
• W2000257039 hasConceptScore W2000257039C62520636 @default.
• W2000257039 hasConceptScore W2000257039C8010536 @default.
• W2000257039 hasIssue "4" @default.
• W2000257039 hasLocation W20002570391 @default.
• W2000257039 hasLocation W20002570392 @default.
• W2000257039 hasOpenAccess W2000257039 @default.
• W2000257039 hasPrimaryLocation W20002570391 @default.
• W2000257039 hasRelatedWork W181149377 @default.
• W2000257039 hasRelatedWork W1971978554 @default.
• W2000257039 hasRelatedWork W1983977711 @default.
• W2000257039 hasRelatedWork W2038599716 @default.
• W2000257039 hasRelatedWork W2055516335 @default.
• W2000257039 hasRelatedWork W2060051479 @default.
• W2000257039 hasRelatedWork W2077818984 @default.
• W2000257039 hasRelatedWork W2082703783 @default.
• W2000257039 hasRelatedWork W2251272965 @default.
• W2000257039 hasRelatedWork W3150066105 @default.
• W2000257039 hasVolume "47" @default.
• W2000257039 isParatext "false" @default.
• W2000257039 isRetracted "false" @default.
• W2000257039 magId "2000257039" @default.
• W2000257039 workType "article" @default.